- Water Content Test Definition: The water content test in insulating oil is defined as a process using Karl Fischer Titration to measure water levels.
- Karl Fischer Principle: The Karl Fischer principle involves a chemical reaction between water and other reagents to determine water content.
- Electrolysis Role: Electrolysis produces iodide ions, which react with water in the solution.
- Detection of Reaction Endpoint: Platinum electrodes detect the endpoint of the Karl Fischer reaction when no more water is present.
- Calculation of Water Content: Using the electricity consumed during the reaction, the exact quantity of water in the insulating oil is calculated.
To measure water content in insulating oil, we use Karl Fischer Titration. In this method, water (H2O) reacts chemically with iodine (I2), sulfur dioxide (SO2), an organic base (C5H5N), and alcohol (CH3OH) in an organic solvent.
The sample is mixed with sulfur dioxide, iodide ions, and an organic base/alcohol. Iodine is generated by electrolysis of the iodide and takes part in the reactions. As long as the reaction continues, no free iodine remains in the solution.
The iodine generated by electrolysis is consumed as long as water molecules are present. When there is no more water to react, the Karl Fischer reactions stop. Two platinum electrodes in the solution detect this endpoint. The presence of free iodine after the reaction changes the voltage between the electrodes, indicating the reaction’s end.
According to Faraday law of electrolysis, the amount of iodine generated is proportional to the electricity consumed for electrolysis during the Karl Fischer reactions.
By measuring the electricity consumed until the reaction ends, we can calculate the actual mass of iodine involved. From the reaction equation, we know that one mole of iodine reacts with one mole of water. Therefore, about 254 grams of iodine will react with 18 grams of water. This allows us to determine the exact amount of water in the insulating oil sample.
